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If it's glass, you should be very, very careful not to let the hot water touch the cold glass. This could cause it to shatter. Avoid using direct heat on it for the same reason. Try a damp towel to grip the lid and turn. Most refrigerated jars have been opened already, and may be stuck because of dried food or condiments between the lid and the jar. Try using warm water, instead of hot to try to rehydrate the dried bits and make it easier to twist the lid.
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