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That's a very wide time range. Really, this article explains well what the best times to water plants are. The ideal time to water them is in the morning before 10 am. 6 am would be good; 3 am is a bit early but also okay. The worst time to water is between 10 am and 2 pm, when the sun is hottest. Late afternoon through around 6 pm, or even later in the summer when days are long, is okay.
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