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I'd think you might not get the amazing smoked flavor any other way than smoking the neck bones, but you could try cooking them in the oven with lots of spices and just a little bit of liquid smoke. It's a pretty good second choice, but use very little....like 3-4 drops for several neck bones. It's a tricky addition, even just a little too much will literally ruin a recipe like a sauce. I don't think it would do too much damage to bones if it's a little heavy, but I would put it in with any liquids in the pan, not on the bones.

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