Which of the following is formed when ethanoic acid is warmed with `HN_(3)` in the presence of conc. `H_(2)SO_(4)` ?

Question

Which of the following is formed when ethanoic acid is warmed with `HN_(3)` in the presence of conc. `H_(2)SO_(4)` ?

Which of the following is formed when ethanoic acid is warmed with `HN_(3)` in the presence of conc. `H_(2)SO_(4)` ?
A. Methylamine
B. Ethanamide
C. Ethanamine
D. Oxamide.

Monjur Alahi

4 views

2025-01-04 04:42

1 Answers

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Salim Ahmed Kawsar · Accepted Answer · 2023-02-05T15:29:48+06:00

Correct Answer - A
This reaction is Schmidt reaction. It involves the formation of `RNH_(2)` from `RCOOH`, when the later is warmed with hydrazoic acid in the presence of conc. `H_(2)SO_(4)`.
`RCOOH+HN_(3) overset("conc. "H_(2)SO_(4)) RNH_(2)+CO_(2)+N_(2)`
`CH_(3)COOH + HN_(3) overset("conc. "H_(2)SO_(4))(rarr) CH_(3)NH_(2)+CO_(2)+N_(2)`