The decomposition of A into product has value of K as 4.5 x 103 sec-1 at 10º C and energy of activation 60 kJ/mol. At what temperature would K be 1.5 x 104 sec-1 .
(a) Kc=[PCl3] [Cl2] / [PCl5]
(b) 120.48
(c) (i) equilibrium will shift on RHS.
(ii) equilibrium will shift on LHS.
(iii) equilibrium will shift on RHS.
(c) : In BF3, B is sp2 hybridised and has a vacant 2p-orbital which overlaps laterally with a filled 2p-orbital of F forming strong pp-pp bond. However in CF4, C...
The energy required to form the intermediate called activated complex is known as activation energy. Activation energy = Threshold energy – Average energy of the reactants