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That will depend on the herbicide and the crop, because there are wide-spectrum herbicides, such as RoundUp or glyphosate, and there are specific ones. The specific ones are generally directed to be against side leaf plants or narrow leaf plants (affecting one type but not the other). Whether it is specific or not should be written on the label. If it is a wide-spectrum one, it should be applied away from the crop, or even better, before the crop seed is even in the soil.

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