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Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is
For the reaction, A = X + Y, the respective concentrations are CA, CX and CY. The forward reaction rate constant is kf and the backward reaction rate constant is kb. Choose the correct statement from the following:
P. At equilibrium, kf CA > kB CxCy
Q. If the reaction is irreversible than, kb CXCY = 0
R. The backward reaction rate will essentially be first order, if the forward reaction rate is first order.
S. Activation energy for the first order forward reaction will be independent of temperature.
In the reaction,
Basics of Organic Reaction Mechanism mcq question image
if the concentration of both the reagents is doubled then the rate of the reaction will
For the chemical reaction P → Q, it is found that the rate of reaction doubles as the concentration of 'P' is doubled. If the reaction rate is proportional to Cpn, then what is the value of 'n' for this chemical reaction
For the chemical reaction P → Q, it is found that the rate of reaction doubles as the concentration of 'P' is doubled. If the reaction rate is proportional to Cpn, then what is the value of 'n' for this chemical reaction
In a batch process, the reaction takes place in the presence of an acid medium. The acid is drained from the reaction vessel at the rate of 15ml/s as a result of the density difference of the acid from the reacting component. To avoid wastage of acid, it is recycled to an acid tank which has 1000 L capacity. The acid drained from the reaction vessel, picks up 50 g/L solids from the reactor. Acid is fed once again to the process from acid tank. When the process is started, the acid is almost pure in the tank as a result of filtration. As the reaction proceeds, acid in the tank gets more and more contaminated with the solids. The concentration of the solids should not exceed 100 g/L from the process point of view. The batch time is 16h. Estimate whether the concentration of the solids will exceed 100g/L during the batch reaction.
The value of 'n' for a chemical reaction A → B, whose reaction rate is → CAn, will be __________ if the rate of the reaction increases by a factor of 8, when the concentration of is doubled.
In an arithmetic progression (AP), the 9th term is 5 times the 2nd term and the 8th term is 1 more than 10 times the first term. What is the 4th term of the geometric progression (GP) whose first term is the second term of AP and whose common ratio is equal to the common difference of AP?
The rate law for a reaction between the substances A and B is given by rate = Kn m. On doubling the concentration of A and halving the concentration of B. What will be the ratio of the new rate of the earlier rate of the reaction?
Which of the following variations are true in piece part production? 1. Piece-to-piece variation 2. Time-to-time variation 3. Within-piece variation 4. Process-to-process variation