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Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is
For the reaction, A = X + Y, the respective concentrations are CA, CX and CY. The forward reaction rate constant is kf and the backward reaction rate constant is kb. Choose the correct statement from the following:
P. At equilibrium, kf CA > kB CxCy
Q. If the reaction is irreversible than, kb CXCY = 0
R. The backward reaction rate will essentially be first order, if the forward reaction rate is first order.
S. Activation energy for the first order forward reaction will be independent of temperature.
In a reaction, A + B → Product, when the concentration of B is doubled the rate is doubled, and when the concentrations of both the reactant doubled the rate is increased by a factor of 8, rate law can be written as: 2 b) Rate = k2 c) Rate = k d) Rate = k22
The configurations of the reactant and the product in the following reaction, are
Basics of Organic Reaction Mechanism mcq question image
The concentration of oxygen at the inner surface of the vessel is maintained at a level C depending on the pressure in the vessel, while the concentration at the outer surface is reduced to zero by the escape of oxygen to the surroundings. A steady state will eventually be reached when the concentration everywhere reaches a constant value. Provided D is independent of concentration there will be a single concentration gradient in the wall and the thickness of the wall is L, the flux is given by________________
For the chemical reaction P → Q, it is found that the rate of reaction doubles as the concentration of 'P' is doubled. If the reaction rate is proportional to Cpn, then what is the value of 'n' for this chemical reaction
In the reaction,
Basics of Organic Reaction Mechanism mcq question image
if the concentration of both the reagents is doubled then the rate of the reaction will
The reaction between ethylene and hydrogen bromide to form ethyl bromide is carried out in a continuous reactor. C2H4 + HBr = C2H5Br The product stream is analyzed and found to contain 51.7 mole% C2H5Br and 17.3% HBr. The feed to the reactor contains only ethylene and hydrogen bromide. Calculate the fractional conversion of the limiting reactant and the percentage by which the other reactant is in excess. If the molar flow rate of the feed stream is 165 mol/s, what is the extent of reaction?
In a chemical reaction, the rate of reaction is independent of the reactant concentration, what is it called what?
If n = overall order of a chemical reaction. a = initial concentration of reactant. t = time required to complete a definite fraction of the reaction. Then pick out the correct relationship.