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Overall rate of reaction in a heterogenous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of catalyst, if it does not entail a chain mechanism.

Overall rate of reaction in a heterogenous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of catalyst, if it does not entail a chain mechanism. Correct Answer Proportional to

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The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)
A stream of air at 100 kPa pressure and 300 K is flowing on the top surface of a thin flat sheet of solid naphthalene of length 0.2 m with a velocity of 20 m/sec. The other data are: Mass diffusivity of naphthalene vapor in air = 6 * 10 –6 m2/sec Kinematic viscosity of air = 1.5 * 10 –5 m2.sc Concentration of naphthalene at the air-solid naphthalene interface = 1 * 10 – 5 kmol/m3 Calculate the overage mass transfer coefficient over the flat plate. Note: For heat transfer over a flat plate, convective heat transfer coefficient for laminar flow can be calculated by the equation. Nu = 0.664 ReL1/2 Pr1/3 you may use analogy between mass and heat transfer.
In the reaction,
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if the concentration of both the reagents is doubled then the rate of the reaction will
A solid-oxide fuel cell is fed with carbon monoxide and reacts with air to produce CO2. This reaction will produce 2 electrons which are used to power an electric circuit external to the fuel cell. The reaction equation is shown below: 2CO(g) + O2(g) -> 2CO2(g) ΔHr° = -565.96 kJ/mol This reaction does not occur for other types of fuel cells which use a catalyst, such as polymerelectrolyte membrane or phosphoric-acid fuel cells. The presence of carbon monoxide on the anode side of these types of fuel cells will cause catalyst poisoning, reducing the efficiency and voltage of the fuel cell. Determine the rate of enthalpy change for a carbon dioxide production rate of 208 mol/hr. The extent of the reaction occurring in the fuel cell can be obtained by the following equation: where:
What is the monoisotopic and average mass of valine? Given data: Mass of the most abundant isotope of Carbon (C°)=12.0000, Mass of most abundant isotope of Hydrogen (H°)=1.0078, Mass of most abundant isotope of Oxygen (O°)=15.9949, Mass of most abundant isotope of Nitrogen (N°)=14.0031, The average mass of Carbon (C)=12.011, The average mass of Hydrogen (H)=1.008, The average mass of Oxygen (O)=15.999, The average mass of Nitrogen (N)=14.007.
Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is
Consider a given volume of liquid at a temperature T below Tm with a free energy G’. If some of the atoms of the liquid cluster together to form a small sphere of solid, the free energy of the system will change to G, given by________ (Assume V1 volume of the solid sphere, V2 volume of liquid, A is the solid/liquid interfacial area, γ solid/liquid interface free energy, G1 and G2 are the free energies per unit volume of solid and liquid respectively).
The rate of the heterogenous catalytic reaction A(g) + B(g) → C(g) is given by $$ - {{\text{r}}_{\text{A}}} = \frac{{{\text{k}}.{{\text{K}}_{\text{A}}}.{{\text{p}}_{\text{A}}}.{{\text{P}}_{\text{B}}}}}{{1 + {{\text{K}}_{\text{A}}}.{{\text{P}}_{\text{A}}} + {{\text{K}}_{\text{C}}}.{{\text{p}}_{\text{C}}}}},$$      where KA and KC are the adsorption equilibrium constants. The rate controlling step for this reaction is
The following tetraene upon photolysis gives
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