In a binary system A-B, εAA, εBB and εAB correspond to A-A, B-B and A-B bond energies respectively. The miscibility gap will occur, if

In a binary system A-B, εAA, εBB and εAB correspond to A-A, B-B and A-B bond energies respectively. The miscibility gap will occur, if Correct Answer $${\varepsilon _{AB}}$$

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The limiting condition for the appearance of the miscibility gap in a binary solution is
Where, G is the Gibbs free energy and X is the mole fraction of component Z.