The limiting condition for the appearance of the miscibility gap in a binary solution is
Where, G is the Gibbs free energy and X is the mole fraction of component Z.

The limiting condition for the appearance of the miscibility gap in a binary solution is
Where, G is the Gibbs free energy and X is the mole fraction of component Z. Correct Answer $$\left( {\frac{{{\partial ^2}G}}{{\partial {X^2}}}} \right) = 0$$

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