Which of the following processes doesn’t come under phyto-remediation of halogen reactions?

Which of the following processes doesn’t come under phyto-remediation of halogen reactions? Correct Answer Concentration and excavation

Bio-accumulation, Phytoextraction, pytostabilisation is collectively known as phytoremediation and concentration and excavation is a physical method of treatment of contaminants and doesn’t require the use of plants.

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In which of the following cases will the compound be a tertiary (3°) halogen compound? (X=halogen atom)