Which of the following is an initiator molecule in the free radical polymerisation?

Which of the following is an initiator molecule in the free radical polymerisation? Correct Answer Benzoyl peroxide

The whole process of free radical polymerisation starts off with a molecule called an initiator. This is a molecule like benzoyl peroxide. When they split, the pair of electrons in the bond which is broken will separate. This is unusual as electrons like to be in pairs whenever possible. When this split happens, we’re left with two fragments, called initiator fragments.

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Consider following data for bulk polymerization, with benzoyl peroxide as initiator. = 6 mol/m3 = 6.56*103 mol/m3 kp2/kt = 1.5*10-6 m3/ mol-s What is the initiator efficiency if initial rate of polymerization is 0.0256 m3/ mol-s benzoyl peroxide decomposes at a rate of 3.2* 10-6 m3/ mol-s-1?
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