Which of the given statements about hard water is/are correct: 1. Contains sulfates, chlorides, bicarbonates of calcium and magnesium. 2. Hard water forms lather with both soap and detergent.

Which of the given statements about hard water is/are correct: 1. Contains sulfates, chlorides, bicarbonates of calcium and magnesium. 2. Hard water forms lather with both soap and detergent. Correct Answer Only 1

The correct answer is Only 1 

CONCEPT:

  • Hard water is water that contains calcium and magnesium salts in the form of bicarbonates, chlorides and sulfates.


EXPLANATION:

  • Hard water does not form lather with soap.
  • It forms scum/precipitate with soap.
  • Sodium stearate in soap reacts with calcium/magnesium and forms calcium stearate or magnesium stearate.
  • Ca2+ + RCOONa → RCOOCa + 2Na+
  • Mg2+ + RCOOna → RCOOMg + 2Na+
  • When all the Ca2+ and Mg2+ ions present in hard water precipitated the resulting water becomes soft. So it is not suitable for washing as a lot of soap get wasted.
  • Detergents are ammonium or sulphonate salts of long-chain carboxylic acids.  The charged end of these compounds does not form any insoluble precipitates. Thus they remain effective in hard water.

Hint

  • Statement is about the hardness of water. It is of two type-
  • Temporary hardness is caused by the presence of dissolved bicarbonates of Calcium (Ca(HCO3)2 ), Magnesium (Mg(HCO3)2 ), Iron and other heavy elements.
  • Permanent Hardness is due to the presence of dissolved chlorides and sulphates of Calcium, Magnesium, Iron and other heavy elements.

Related Questions

Assertion (A) : Synthetic detergents can lather when in hard water.Reason (R) : Synthetic detergents form soluble calcium and magnesium salts with hard water.
Assertion (A) : Synthetic detergents can lather when in hard water.
Reason (R) : Synthetic detergents form soluble calcium and magnesium salts with hard water.
Assertion (A) Synthetic detergents can lather well in hard water.
Reason (R) Synthetic detergents form soluble calcium and magnesium salts with hard water.