A 20 L container holds 0.650 mol of He gas at 37°C at a pressure of 628.3 bar. What will be new pressure inside the container if the volume is reduced to 12 L. The temperature is increased to 177°C and 1.25 mol of additional He gas was added to it?

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1 Answers

Given : 

V1 = Initial volume = 20 L, 

n1 = Initial number of moles = 0.650 mol 

P1 = Initial pressure = 628.3 bar 

T1 = Initial temperature = 37°C 

= 37 + 273.15 K 

= 310.15 K 

n2 = Final number of moles = 0.650 + 1.25 

= 1.90 mol, 

V2 = Final volume = 12 L 

T2 = Final temperature = 177°C 

= 177 + 273.15 K 

= 450.15 K, 

R = 0.0821 L atm K-1 mol-1 

To find : 

P = Final pressure 

Formula : 

PV = nRT

Calculation : 

According to ideal gas equation, 

P2V2 = n2RT2.

∴ P2 = \(\frac{n_2RT_2}{V_2}\) 

\(\frac{1.90\times 0.0821 \times 450.15}{12}\) 

= 5.852 atm.

∴ The final pressure of the gas is 5.852 atm.

[Note : In the above numerical, converting the pressure value to different units, we get : 5.852 atm = 4447.52 torr = 5.928 bar]

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