At a certain temperature the following equilibrium is established `CO(g)+NO_2(g)hArrCO_2(g)+NO(g)` One mole of each of the four gas is mixed in one li
At a certain temperature the following equilibrium is established `CO(g)+NO_2(g)hArrCO_2(g)+NO(g)`
One mole of each of the four gas is mixed in one litre container and the reaction is allowed to reach equilibrium state.When excess of baryta water `(Ba(OH)_2)` is added to the equilibrium mixture, the weight of white ppt. `(BaCO_3)` obtained is 236.4 gm.The equilibrium constant `K_C` of the reaction is (Ba=137)
A. 1.2
B. 2.25
C. 2.1
D. 3.6
1 Answers
Correct Answer - B
`{:(,CO(g)+,NO_2(g)hArr , CO_2(g)+,NO(g)),(t=0,"1 mole","1 mole","1 mole","1 mole"),(At eq. , 1-x,1-x,1+x,1+x):}`
`CO_2+Ba(OH)_2 to BaCO_3`
mole of `BaCO_3=263.4/197=1.2`
So mole of `CO_2` at eq. =12
or 1+x=1.2
x=0.2
`K_C=((1+x)/(1-x))^2=((1.2)/(0.8))^2 =2.25`