Name the members of the lanthanoid series which exhibit +4 oxidation state and those
which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic
configurations of these elements.

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1 Answers

The lanthanides that exhibit +2 and +4 states are shown in the given table. The atomic numbers of the elements are given in the parenthesis.

+2 +4
Nd (60) Ce (58)
Sm (62) Pr (59)
Eu (63) Nd (60)
Tm (69) Tb (65)
Yb (70) Dy (66)

Ce after forming Ce4+ attains a stable electronic configuration of [Xe].
Tb after forming Tb4+ attains a stable electronic configuration of [Xe] 4f7.
Eu after forming Eu2+ attains a stable electronic configuration of [Xe] 4f7.
Yb after forming Yb2+ attains a stable electronic configuration of [Xe] 4f14.

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