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A pair-instability supernova is a type of supernova predicted to occur when pair production, the production of free electrons and positrons in the collision between atomic nuclei and energetic gamma rays, temporarily reduces the internal radiation pressure supporting a supermassive star's core against gravitational collapse. This pressure drop leads to a partial collapse, which in turn causes greatly accelerated burning in a runaway thermonuclear explosion, resulting in the star being blown completely apart without leaving a stellar remnant behind.

Pair-instability supernovae can only happen in stars with a mass range from around 130 to 250 solar masses and low to moderate metallicity.

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