1. Carbon dioxide
  2. Carbon monoxide
  3. Chlorofluorocarbons 
  4. Methane gas
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1 Answers

Option 3 : Chlorofluorocarbons 

Chlorofluorocarbons is not a primary contributor to the greenhouse effect. It does not have any a natural source, but is side product of industrial processes or manufactured for human purposes such as cleaning agents, refrigerants, and electrical insulators.

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