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The activation for the climb is equal to _____ where; Uj = Activation for nucleation of jog Uv = Activation for formation of the vacancy Um = Activation for formation of the self diffusion Ui = Activation for formation of the interstitial diffusion
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)
What is the enthalpy change of a reaction at 45oC, if the enthalpy of reactant at 45oC and 25oC are 10 J and 6 J, and enthalpy of product at 45oC and 25oC are 15 J and 8 J, and the enthalpy change of reaction at 25oC is 10 J?
What is the enthalpy change of a reaction at 35oC, if the enthalpy of reactant at 35oC and 25oC are 18 J and 10 J, and enthalpy of product at 35oC and 25oC are 12 J and 8 J, and the enthalpy change of reaction at 25oC is 15 J?
What is the enthalpy change of a reaction at 35oC, if the enthalpy of reactant at 35oC and 25oC are 22 J and 15 J, and enthalpy of product at 35oC and 25oC are 10 J and 5 J, and the enthalpy change of reaction at 25oC is 36 J?
What is the enthalpy change of a reaction at 30oC, if the enthalpy of reactant at 30oC and 25oC are 18 J and 15 J, and enthalpy of product at 30oC and 25oC are 10 J and 8 J, and the enthalpy change of reaction at 25oC is 45 J?
What is the enthalpy change of a reaction at 90oC, if the enthalpy of reactant at 90oC and 25oC are 60 J and 25 J, and enthalpy of product at 90oC and 25oC are 80 J and 10 J, and the enthalpy change of reaction at 25oC is 5 J?
For the reaction, A = X + Y, the respective concentrations are CA, CX and CY. The forward reaction rate constant is kf and the backward reaction rate constant is kb. Choose the correct statement from the following:
P. At equilibrium, kf CA > kB CxCy
Q. If the reaction is irreversible than, kb CXCY = 0
R. The backward reaction rate will essentially be first order, if the forward reaction rate is first order.
S. Activation energy for the first order forward reaction will be independent of temperature.
What is the enthalpy of a mixture having 20% of A with enthalpy 20 J, 30% of B with enthalpy 40 J, and 50% of C with enthalpy 20 J?
What is the enthalpy of a mixture having 10% of A with enthalpy 10 J, 30% of B with enthalpy 30 J, and 60% of C with enthalpy 25 J?