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Pick out the wrong statement below:
I. For the same conversion, the holding time required in a batch reactor, is always equal to the space time required in a PFR.
II. Two mixed reactors of unequal size are available for producing a specified product, formed by a homogenous second order reaction. To achieve maximum production rate, the smaller reactor should be placed in series before the larger reactor.
III. Arrehenius equation describing the effect of temperature on rate constant is given by, $${\text{K}} = {\text{A}}.{{\text{e}}^{ - \frac{{{\text{Ea}}}}{{{\text{RT}}}}}}$$
IV. The mechanism for the decomposition of CH3CHO into CH4 and CO in presence of I2 is:
CH3CHO + I2 → CH3I + HI + CO; slow
CH3I + HI → CH4 + I2; fast
Then the rate of disappearance CH3CHO is equal to K.CCH3l.CHl and acts as a catalyst.

Pick out the wrong statement below:
I. For the same conversion, the holding time required in a batch reactor, is always equal to the space time required in a PFR.
II. Two mixed reactors of unequal size are available for producing a specified product, formed by a homogenous second order reaction. To achieve maximum production rate, the smaller reactor should be placed in series before the larger reactor.
III. Arrehenius equation describing the effect of temperature on rate constant is given by, $${\text{K}} = {\text{A}}.{{\text{e}}^{ - \frac{{{\text{Ea}}}}{{{\text{RT}}}}}}$$
IV. The mechanism for the decomposition of CH3CHO into CH4 and CO in presence of I2 is:
CH3CHO + I2 → CH3I + HI + CO; slow
CH3I + HI → CH4 + I2; fast
Then the rate of disappearance CH3CHO is equal to K.CCH3l.CHl and acts as a catalyst. Correct Answer IV

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Consider the following statements.
1. The chain reaction process is used in nuclear bombs to release a vast amount of energy, but in nuclear reactors, there is no chain reaction.
2. In a nuclear reactor, the reaction is controlled, while in nuclear bombs, the reaction is uncontrolled.
3. In a nuclear reactor, all operating reactors are 'critical', while there is no question of 'critically' in case of a nuclear bomb.
4. Nuclear reactors do not use moderators, while nuclear bombs use them.
Which of the above statements about operational principles of a nuclear reactor and a nuclear bomb is/are correct?
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P. At equilibrium, kf CA > kB CxCy
Q. If the reaction is irreversible than, kb CXCY = 0
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S. Activation energy for the first order forward reaction will be independent of temperature.
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