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More complex carbohydrates occur in nature when 2 or more simple sugars are linked altogether. In nature, the linkages are _________ linkages, that’s, acetal or ketal bonds involving the anomeric carbon of just one of the monosaccharides involved. These bonds are called _________ linkages.
Analysis of a hexapeptide using enzymatic cleavage reveals the following result:
• Amino acid composition of the peptide is: 2R, A, V, S, Y
• Trypsin digestion yields two fragments and the compositions are: (R, A, V) and (R, S, Y)
• Chymotrypsin digestion yields two fragments and the compositions are: (A, R, V, Y) and (R, S)
• Digestion with carboxypeptidase A yields no cleavage product.
Given: Trypsin cleaves at carboxyl side of R. Chymotrypsin cleaves at carboxyl side of Y. Carboxypeptidase A cleaves at amino side of the C-terminal amino acid (except R and K) of the peptide.
The correct amino acid sequence of the peptide is:
The percentage SIMILARITIES and IDENTITIES, respectively, between the two peptide sequences given below will be . . . . . . . . % and . . . . . . . . %.
Peptide I: Ala-Ala-Arg-Arg-Gln-Trp-Leu-Thr-Phe-Thr-Lys-Ile-Met-Ser-Glu
Peptide II: Ala-Ala-Arg-Glu-Gln-Tyr-Ile-Ser-Phe-Thr-Lys-Ile-Met-Arg-Asp
Which is the correct order of activities showcased by exogenous pathway? i) Generation of MHC class II molecules ii) MHC-peptide transport iii) Class II MHC peptide loading iv) Generation of Peptide from proteolysis
For the reaction, A = X + Y, the respective concentrations are CA, CX and CY. The forward reaction rate constant is kf and the backward reaction rate constant is kb. Choose the correct statement from the following:
P. At equilibrium, kf CA > kB CxCy
Q. If the reaction is irreversible than, kb CXCY = 0
R. The backward reaction rate will essentially be first order, if the forward reaction rate is first order.
S. Activation energy for the first order forward reaction will be independent of temperature.
In a batch process, the reaction takes place in the presence of an acid medium. The acid is drained from the reaction vessel at the rate of 15ml/s as a result of the density difference of the acid from the reacting component. To avoid wastage of acid, it is recycled to an acid tank which has 1000 L capacity. The acid drained from the reaction vessel, picks up 50 g/L solids from the reactor. Acid is fed once again to the process from acid tank. When the process is started, the acid is almost pure in the tank as a result of filtration. As the reaction proceeds, acid in the tank gets more and more contaminated with the solids. The concentration of the solids should not exceed 100 g/L from the process point of view. The batch time is 16h. Estimate whether the concentration of the solids will exceed 100g/L during the batch reaction.
A chain growth polymerisation reaction consists of three different types of reaction namely initiation reaction, propagation reaction & termination reaction. Chain growth polymerisation reaction is not involved in the manufacture of
For a reaction, the extent of reaction equation is Ni = Nio + ϒVi is Where: Ni = Moles of species I present in the system after the reaction occurs Nio = Moles of species I present in the system when the reaction starts Vi = Stoichiometric coefficient for species i in the specified chemical reaction equation ϒ = Extent of reaction
Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is
In the reaction,
Basics of Organic Reaction Mechanism mcq question image
if the concentration of both the reagents is doubled then the rate of the reaction will