Related Questions

The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)
The activation for the climb is equal to _____ where; Uj = Activation for nucleation of jog Uv = Activation for formation of the vacancy Um = Activation for formation of the self diffusion Ui = Activation for formation of the interstitial diffusion
For the reaction, A = X + Y, the respective concentrations are CA, CX and CY. The forward reaction rate constant is kf and the backward reaction rate constant is kb. Choose the correct statement from the following:
P. At equilibrium, kf CA > kB CxCy
Q. If the reaction is irreversible than, kb CXCY = 0
R. The backward reaction rate will essentially be first order, if the forward reaction rate is first order.
S. Activation energy for the first order forward reaction will be independent of temperature.
Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is
The steady-state creep activation energy is given by the Arrhenius type rate equation ε = Ae-(Q/RT), where, Q = activation for rate-controlling step A = pre-exponent complex constant containing the frequency of vibration of the flow unit T = absolute temperature R = Universal gas constant The slope of the equation for log ε vs. log T plot will be equal to __________
The rate law for a reaction between the substances A and B is given by rate = Kn m. On doubling the concentration of A and halving the concentration of B. What will be the ratio of the new rate of the earlier rate of the reaction?
Two refrigerators M and N operate in series. The refrigerator M absorbs energy at the rate of 1 kW from a body at temperature 400 K and rejects energy as heat to a body at a temperature T. The refrigerator N absorbs the same quantity of energy which is rejected by the refrigerator N from the body at temperature T, and rejects energy as heat to a body at temperature 800 K. If both the refrigerators have the same C.O.P., what is the value temperature T?
Which of the following are true? (i) A programming language option does not permit global variables of any king and has no nesting of procedures/functions, but permits recursion can be implemented with static storage allocation (ii) Multi-level access link (or display) arrangement is needed to arrange activation records-only if the programming language being implemented has nesting of procedures/function (iii) Recursion in programming languages cannot be implemented with dynamic storage allocation (iv) Nesting of procedures/functions and recursion require a dynamic heap allocation scheme and cannot be implemented with a stack-based allocation scheme for activation records (v) Languages which permit a function to return a function as its result cannot be implemented with a stack-based storage allocation scheme for activation records.
The activation energy of creep for a pure metal at high temperature is equal to activation energy of _____________
The minimum energy required to allow a chemical reaction to proceed is termed as the 'threshold energy '. Chemical reaction with low activation energy are