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For the reaction, A = X + Y, the respective concentrations are CA, CX and CY. The forward reaction rate constant is kf and the backward reaction rate constant is kb. Choose the correct statement from the following:
P. At equilibrium, kf CA > kB CxCy
Q. If the reaction is irreversible than, kb CXCY = 0
R. The backward reaction rate will essentially be first order, if the forward reaction rate is first order.
S. Activation energy for the first order forward reaction will be independent of temperature.
Consider the following statements in connection with deflection-type and null-type instruments: 1. Null-type instruments are more accurate than the deflection-type ones. 2. Null-type of instrument can be highly sensitive compared to a deflection-type instrument. 3. Under dynamic conditions, null-type instruments are less preferred to deflection-type instruments. 4. Response is faster in null-type instruments as compared to deflection-type instruments. Which of the above statements are correct?
A chain growth polymerisation reaction consists of three different types of reaction namely initiation reaction, propagation reaction & termination reaction. Chain growth polymerisation reaction is not involved in the manufacture of
For a reaction, the extent of reaction equation is Ni = Nio + ϒVi is Where: Ni = Moles of species I present in the system after the reaction occurs Nio = Moles of species I present in the system when the reaction starts Vi = Stoichiometric coefficient for species i in the specified chemical reaction equation ϒ = Extent of reaction
Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is
In the reaction,
Basics of Organic Reaction Mechanism mcq question image
if the concentration of both the reagents is doubled then the rate of the reaction will
Following table represents the type of reactions of three metals with various solutions. Metal lron (II) Sulphate Copper (II) Sulphate Zinc Sulphate A No reaction Displacement Not known B No reaction No reaction No reaction C Displacement Not known No reaction Which of the following represents the correct order of reactivity of metals A, B, C
Consider the following grammar and the semantic actions to support the inherited type declaration attributes. Let X1, X2, X3, X4, X5 and X6 be the placeholders for the non-terminals D, T, L or L1 in the following table: Production rule Semantic action D → T L X1.type = X2.type T → int T.type = int T → float T.type = float L → L1, id X3.type = X4.type addType(id.entry, X5.type) L → id addType(id.entry, X6.type)   Which one of the following are the appropriate choices for X1, X2, X3 and X4?
In a batch process, the reaction takes place in the presence of an acid medium. The acid is drained from the reaction vessel at the rate of 15ml/s as a result of the density difference of the acid from the reacting component. To avoid wastage of acid, it is recycled to an acid tank which has 1000 L capacity. The acid drained from the reaction vessel, picks up 50 g/L solids from the reactor. Acid is fed once again to the process from acid tank. When the process is started, the acid is almost pure in the tank as a result of filtration. As the reaction proceeds, acid in the tank gets more and more contaminated with the solids. The concentration of the solids should not exceed 100 g/L from the process point of view. The batch time is 16h. Estimate whether the concentration of the solids will exceed 100g/L during the batch reaction.
In the reaction,
Basics of Organic Reaction Mechanism mcq question image
the major product X is