The internal energy of a system is dependent on the following aspects: 1) Molecular weight 2) Molecular structure 3) Degree of molecular activity Which of the above are correct?

The internal energy of a system is dependent on the following aspects: 1) Molecular weight 2) Molecular structure 3) Degree of molecular activity Which of the above are correct? Correct Answer 1, 2 and 3

Explanation:

  • There are two types of internal energy of a system i.e. macroscopic and microscopic.
  • From a thermodynamic point of view, we will focus on the microscopic approach i.e. at the molecular level.
  • The microscopic energy consists of energy at the molecular level e.g. molecular rotation, vibration, etc. and energy at the nuclear level is also involved.
  • The rotational and vibrational energy also depends upon the molecular structure e.g. inertia of molecules depends upon how the atoms are arranged.
  • So, the internal energy of a system is dependent on molecular structure and the degree of molecular activity. 
  • Internal energy is an extensive property, so it depends on mass and volume, hence it depends on molecular weight.

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