Magnesium strip slowly tarnishes on keeping in air but metallic calcium is readily attacked by air. Explain.

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1 Answers

  • The reactivity of group 2 metals increases with increasing atomic radius and lowering of ionization enthalpy down the groups.
  • Thus, calcium has lower ionization enthalpy. Therefore, calcium is more reactive than magnesium.
  • Hence, Mg reacts slowly with air forming a thin film of oxide resulting into tarnishing, whereas Ca reacts readily at room temperature with oxygen and nitrogen in the air.

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