Explain the following steps with respect to the process of crystallization.

i. Preparation of a saturated solution :

• A saturated solution of the crude solid is prepared by boiling it in a small but sufficient quantity of a suitable solvent.
• On doing so the main solute forms an almost saturated solution, but the solution is not saturated with respect to the soluble impurities, as they are in small proportion.

ii. Hot filtration : 

The hot saturated solution is quickly filtered to remove undissolved impurities as residue. Filtration under suction can be employed for rapid filtration.

iii. Cooling of the filtrate :

• The hot filtrate is allowed to cool. 
• On cooling, the filtrate becomes supersaturated with respect to the main dissolved solute because solubility of a substance decreases with lowering of temperature. 
• The excess quantity of the dissolved solute comes out of the solution in the form of crystals.
• The dissolved impurities, however, do not supersaturate the solution, as their quantity is small.
• These continue to stay in the solution in dissolved state even on cooling. Therefore, the separated crystals are free from soluble impurities.

iv. Filtration :

• The crystals obtained on cooling are further purified by filtration to remove insoluble impurities.
• The filtrate obtained is called as mother liquor.
• The crystals obtained after filtration are free from soluble as well as insoluble impurities.