In \( III ^{ rd } \) group of salt analysis for cations \( NH _{4} Cl \) and \( NH _{4} OH \) are added as group reagents. Which of the following can be used instead of \( NH _{4} Cl \) ? (a) \( NaCl \) (b) \( \left( NH _{4}\right)_{2} SO _{4} \) (c) \( \left( NH _{4}\right)_{2} C _{2} O _{4} \) (d) \( NH _{4} NO _{3} \)

Question

In \( III ^{ rd } \) group of salt analysis for cations \( NH _{4} Cl \) and \( NH _{4} OH \) are added as group reagents. Which of the following can be used instead of \( NH _{4} Cl \) ? (a) \( NaCl \) (b) \( \left( NH _{4}\right)_{2} SO _{4} \) (c) \( \left( NH _{4}\right)_{2} C _{2} O _{4} \) (d) \( NH _{4} NO _{3} \)

Monjur Alahi

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2025-01-04 04:42

1 Answers

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Salim Ahmed Kawsar · Accepted Answer · 2023-02-05T15:29:48+06:00

Salim Ahmed Kawsar

d) NH₄NO₃

As it provides NH⁺₄ ions which suppresses the ionisation of NH₄OH so that only the group 3rd cations are precipitated as hydroxides because of their low solubility products and NO⁻₃ ions do not produce precipitate with the cations of IVth,Vth and VIth groups.

8 views Answered 2023-02-05 15:29