Tert-butyl methyl ether on heating with anhydrous HI in ether gives

Question

Tert-butyl methyl ether on heating with anhydrous HI in ether gives

Tert-butyl methyl ether on heating with anhydrous HI in ether gives
A. `CH_(3)OH+(CH_(3))_(3)Cl`
B. `CH_(3)I+(CH_(3))_(3)COH`
C. `CH_(3)I+(CH_(3))_(3)Cl`
D. None of the above

Monjur Alahi

6 views

2025-01-04 04:42

1 Answers

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Salim Ahmed Kawsar · Accepted Answer · 2023-02-05T15:29:48+06:00

Correct Answer - B
If favours `S_(N)2` reaction and the nucleophile `I^(-)` attacks the less hindered methyl group.
`I^(-)+CH_(3)-overset(o+)underset(H)underset(|)O-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(3)overset(S_(N)2)rarrCH_(3)I+CH_(3)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-OH`