From amongst the following alcohols the one that would react fastest with conc. HCl and anhydrous ZnCl2, is

(1) 2–Butanol 

(2) 2–Methylpropan–2–ol 

(3) 2–Methylpropanol 

(4) 1–Butanol

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1 Answers

(2)

3° alcohols react fastest with ZnCl2/conc.HCl due to formation of 3° carbocation and\2–methyl propan–2–ol is the only 3° alcohol

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