An oxidising agent is needed in the iodination of methane but not in the chlorination or bromination . Assign reason-
An oxidising agent is needed in the iodination of methane but not in the chlorination or bromination . Assign reason-
1 Answers
In the iodination of methane, H-I is also formed as the product along with iodomethane. Since it is a strong reducing agent, it reduces iodomethane back to methane and makes the reaction reversible. In order to destroy HI, oxidising agents like HIO3(or HNO3) is needed. But HCl and HBr formed in the chlorination and bromination reaction of methane are not in a position to react with the monosubstituted product, Since they are comparatively weak reducing agents. Therefore, no oxidising agents are needed for these reactions.
CH4+ I2 ------> CH3I+ HI
(Methane)
5HI + HIO3 ----------> 3H2O + 3I2