Discuss the preparation of alkanes by Wurtz reaction. What is the limitation of the reaction?

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Wurtz synthesis: Higher alkanes are prepared by heating an alkylhalide (RX) with sodium metal in dry ether solution. 

R-X +2Na + XR dry ether -------> R-R + 2NaX 

CH3Br + 2Na + BrCH3 dry ether -------> CH3CH3 + 2NaBr 

Limitations: - use of two different alkyl holds in Wurtz Rxn always leads to a mixture of alkanes; those are difficult to separate because of little B.pt difference. So only symmetrical alkanes can be prepared by this method.

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