Which of the following pairs represents linkage isomers ?
Which of the following pairs represents linkage isomers ?
(a) [Cu(NH3)4][PtCl4] and [Pt(NH3)4][CuCl4]
(b) [Pd(PPh3)2(NCS)2] and [Pd(PPh3)2(SCN)2]
(c) [Co(NH3)5(NO3)]SO4 and [Co(NH3)5(SO4)]NO3
(d) [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2
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(b) : Linkage isomerism is exhibited by compounds containing ambidentate ligand.
In[Pd(PPh3)2(NCS)2], the linkage of NCS and Pd is through N.
In [Pd(PPh3)2(SCN)2], the linkage of SCN and Pd is through S.
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