Explain the following :
(i) CO is stronger ligand than NH3.
(ii) Low spin octahedral complexes of nickel are not known.
(iii)Aqueous solution of [Ti(H2O)6]+3 is coloured.

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1 Answers

(i) CO has high value of crystal field splitting energy than Cl.
(ii) Ni has d8 conguration which does not affect by field strength of ligand.
(iii) In this case, Ti+3 has t2g 1 eg 0 configuration. It can perform d-d transition.

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