Why does nitrogen show catenation properties less than phosphorus?


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Catenation is much more common in phosphorous compounds than in nitrogencompounds. This is because of the relative weakness of the N−N single bond as compared to the P−P single bond. Since nitrogen atom is smaller, there is greater repulsion of electron density of two nitrogen atoms, thereby weakening the N−N single bond.

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The property of catenation depends upon the strength of the element bond. Since the N- N (159 kJ mol-1) bond strength is much weaker than P-P (213 kJ mol-1) bond strength, therefore nitrogen show less catenation properties than phosphorus.

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