Define electronegativity. How does it differ from electron gain enthalpy?
Define electronegativity. How does it differ from electron gain enthalpy?
2 Answers
Electronegativity is the ability of an atom in a chemical compound to attract a bond pair of electrons towards itself. Electronegativity of any given element is not constant. It varies according to the element to which it is bound. It is not a measurable quantity. It is only a relative number. On the other hand, electron gain enthalpy is the enthalpy change that takes place when an electron is added to a neutral gaseous atom to form an anion. It can be negative or positive depending upon whether the electron is added or removed. An element has a constant value of the electron gain enthalpy that can be measured experimentally.
Electronegativity: Electronegativity of an element may be defined as the tendency of its atom to attract the shared pair of electron towards itself in a covalent bond.
| Electron gain enthalpy | Electronegativity |
| 1. It is the tendency of an atom to attract outside electron. | 1. It is the tendency of an atom to attract shared pair of electrons. |
| 2. It is the absolute electron attracting tendency of the atom. | 2. It is the relative electron attracting tendency of an atom. |
| 3. It is the property of an isolated atom. | 3. It is the property of bonded atom. |
| 4. The elements with symmetrical configuration have almost zero electron affinities. | 4. The elements with symmetrical configuration have specific electronegativities. |
| 5. It has certain units i.e., kJ mol-1 and eV/atom. | 5. It has no units. |