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When we toss a coin, the possible outcomes are only two, head or tail, which are equally likely outcomes. Therefore, the result of an individual toss is completely unpredictable.
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When an unbiased coin is tossed the chances of getting a head or tail are equally likely. So both teams get team equal and fair chances to try their luck. So tossing a coin considered to be a fair way of deciding which team should get the ball at the beginning of a football game.
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