The colour of ferrous sulphate crystals is green. On heating, FeSO4.7H2O first decomposes to form anhydrous ferrous sulphate (FeSO4) which is white in colour.
When barium chloride solution and sodium sulphate solution are mixed together, an insoluble salt is formed, which is barium sulphate, and white in colour.
BaCl2(aq) + Na2SO4(aq) → BaSO4(s) ↓ +...