1 Answers
Anions are larger than cations. Large sized anions occupy lattice sites, while small sized cations are found in voids. The ratio of radius of cation to anion is called radius ratio.
In condensed matter physics and inorganic chemistry the cation-anion radius ratio is the ratio of the ionic radius of the cation to the ionic radius of the anion in a cation-anion compound. This is simply given by r C / r A {\displaystyle r_{C}/r_{A}}.
According to Pauling's rules for crystal structures, the allowed size of the cation for a given structure is determined by the critical radius ratio. If the cation is too small, then it will attract the anions into each other and they will collide hence the compound will be unstable due to anion-anion repulsion; this occurs when the radius ratio drops below 0.155.
At the stability limit the cation is touching all the anions and the anions are just touching at their edges. For radius ratios greater than 0.155, the compound may be stable.