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Methylammonium tin halides are solid compounds with perovskite structure and a chemical formula of CH3NH3SnX3, where X = I, Br or Cl. They are promising alternatives to the led-free perovskites as the photoactive materials. Tin-based perovskites have shown excellent mobility in transistors which gives them an opportunity to be explored more for solar cell applications.

Sn-based perovskites, despite being regarded as semiconductors, often display metallic-like behavior due to the inadvertent and/or spontaneous hole carrier doping resulting from the easy oxidation of Sn to Sn.

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