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In physics, the optical theorem is a general law of wave scattering theory, which relates the forward scattering amplitude to the total cross section of the scatterer. It is usually written in the form
where f is the scattering amplitude with an angle of zero, that is the amplitude of the wave scattered to the center of a distant screen and k is the wave vector in the incident direction.
Because the optical theorem is derived using only conservation of energy, or in quantum mechanics from conservation of probability, the optical theorem is widely applicable and, in quantum mechanics, σ t o t {\displaystyle \sigma _{\mathrm {tot} }} includes both elastic and inelastic scattering.
The generalized optical theorem, first derived by Werner Heisenberg, allows for arbitrary outgoing directions k':