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Diruthenium tetraacetate chloride is the coordination polymer with the formula {4]Cl}n. A red brown solid, the compound is obtained by the reduction of ruthenium trichloride in acetic acid. The compound has attracted much academic interest because it features a fractional metal-metal bond order of 2.5.
The 4] core adopts the Chinese lantern structure, with four acetate ligands spanning the Ru2 center. The Ru-Ru distance is 228 pm. The 4] cages are linked by bridging chloride ligands.
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