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methyllithium is classified both as an organolithium compound and an organosilicon compound. It has the empirical formula LiCH2Si3, often abbreviated LiCH2tms. It crystallizes as the hexagonal prismatic hexamer 6, akin to some polymorphs of methyllithium. Many adducts have been characterized including the diethyl ether complexed cubane 42] and 22].
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