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Miller indices form a notation system in crystallography for lattice planes in crystal lattices.
In particular, a family of lattice planes of a given Bravais lattice is determined by three integers h, k, and ℓ, the Miller indices. They are written , and denote the family of lattice planes orthogonal to g h k ℓ = h b 1 + k b 2 + ℓ b 3 {\displaystyle \mathbf {g} _{hk\ell }=h\mathbf {b_{1}} +k\mathbf {b_{2}} +\ell \mathbf {b_{3}} } , where b i {\displaystyle \mathbf {b_{i}} } are the basis or primitive translation vectors of the reciprocal lattice for the given Bravais lattice. This is based on the fact that a reciprocal lattice vector g {\displaystyle \mathbf {g} } is the wavevector of a plane wave in the Fourier series of a spatial function which periodicity follows the original Bravais lattice, so wavefronts of the plane wave are coincident with parallel lattice planes of the original lattice. Since a measured scattering vector in X-ray crystallography, Δ k = k o u t − k i n {\displaystyle \mathbf {\Delta k} =\mathbf {k} _{\mathrm {out} }-\mathbf {k} _{\mathrm {in} }} with k o u t {\displaystyle \mathbf {k} _{\mathrm {out} }} as the outgoing X-ray wavevector and k i n {\displaystyle \mathbf {k} _{\mathrm {in} }} as the incoming X-ray wavevector, is equal to a reciprocal lattice vector g {\displaystyle \mathbf {g} } as stated by the Laue equations, the measured scattered X-ray peak at each measured scattering vector Δ k {\displaystyle \mathbf {\Delta k} } is marked by Miller indices. By convention, negative integers are written with a bar, as in 3 for −3. The integers are usually written in lowest terms, i.e. their greatest common divisor should be 1. Miller indices are also used to designate reflections in X-ray crystallography. In this case the integers are not necessarily in lowest terms, and can be thought of as corresponding to planes spaced such that the reflections from adjacent planes would have a phase difference of exactly one wavelength , regardless of whether there are atoms on all these planes or not.
There are also several related notations:
In the context of crystal directions , the corresponding notations are: