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Rubidium bromide is the bromide of rubidium. It has a NaCl crystal structure, with a lattice constant of 685 picometres.

There are several methods for synthesising rubidium bromide. One involves reacting rubidium hydroxide with hydrobromic acid:

Another method is to neutralize rubidium carbonate with hydrobromic acid:

Rubidium metal would react directly with bromine to form RbBr, but this is not a sensible production method, since rubidium metal is substantially more expensive than the carbonate or hydroxide; moreover, the reaction would be explosive.

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