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Bismuth iodide is the inorganic compound with the formula BiI3. This gray-black salt is the product of the reaction of bismuth and iodine, which once was of interest in qualitative inorganic analysis.

Bismuth iodide adopts a distinctive crystal structure, with iodide centres occupying a hexagonally closest-packed lattice, and bismuth centres occupying either none or two-thirds of the octahedral holes , therefore it is said to occupy one third of the total octahedral holes.

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