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Dimeric sulfenic chloride
Disulfur dichloride is the inorganic compound of sulfur and chlorine with the formula S2Cl2.
Some alternative names for this compound are sulfur monochloride , disulphur dichloride and sulphur monochloride. S2Cl2 has the structure implied by the formula Cl−S−S−Cl, wherein the angle between the Cl−S−S and S−S−Cl planes is 90°. This structure is referred to as gauche, and is akin to that for H2O2. A rare isomer of S2Cl2 is S=SCl2; this isomer forms transiently when S2Cl2 is exposed to UV-radiation.
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