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Triplet oxygen, O2, refers to the S = 1 electronic ground state of molecular oxygen. It is the most stable and common allotrope of oxygen. Molecules of triplet oxygen contain two unpaired electrons, making triplet oxygen an unusual example of a stable and commonly encountered diradical: it is more stable as a triplet than a singlet. According to molecular orbital theory, the electron configuration of triplet oxygen has two electrons occupying two π molecular orbitals of equal energy. In accordance with Hund's rules, they remain unpaired and spin-parallel and account for the paramagnetism of molecular oxygen. These half-filled orbitals are antibonding in character, reducing the overall bond order of the molecule to 2 from a maximum value of 3 , which occurs when these antibonding orbitals remain fully unoccupied. The molecular term symbol for triplet oxygen is Σg.

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