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Barium borate is an inorganic compound, a borate of barium with a chemical formula BaB2O4 or Ba2. It is available as a hydrate or dehydrated form, as white powder or colorless crystals. The crystals exist in the high-temperature α phase and low-temperature β phase, abbreviated as BBO; both phases are birefringent, and BBO is a common nonlinear optical material.

Barium borate was discovered and developed by Chen Chuangtian and others of the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences.

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