For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases.

A Decreases
B Increases
C Remains same
D Decreases linearly

Correct Answer: Increases

We know for an ideal binary solution by Lewis-Randall rule fugacity of a component is directly proportional to mole fraction of that component. So basically on increasing the mole fraction the fugacity of the component is increasing but this equation is valid only for an ideal solution but, we can extend this behavior for real solution also under some conditions.
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#Chemical Engineering #Chemical Engineering Thermodynamics

Related Questions

Fugacity of a component in an ideal gas mixture is euqal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at contant pressure and temperature __________ as its mole fraction increases.
A Decreases
B Decreases exponentially
C Increases
D Remains constant
"The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is
A The statement as per Gibbs-Helmholtz
B Called Lewis-Randall rule
C Henry's law
D None of these
Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature.
A Decreases
B Increases
C Remains constant
D Decreases logarithmically
কক্ষ তাপমাত্রায় 1.0 mole এসিটিক এসিড এবং 1.0 mole ইথানলকে মিশ্রিত করা হলো। সাম্যবস্থায় 0.667 mole এসিটিক এসিড ক্রিয়ায় অংশগ্রহণ করলে তার ke এর মান 4.00 হয়। কত মোল এষ্টার উৎপাদিত হবে যদি একই তাপমাত্রায় 4.0 mole এসিড এবং 2.0 mole ইথানাল নেয়া হয়।
A 0.333
B 0.667
C 6.0
D 2.0
Fugacity co-efficient of a substance is the ratio of its fugacity to
A Mole fraction
B Activity
C Pressure
D Activity co-efficient
With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure
A Increases
B Decreases
C Remains same
D Decreases linearly
According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.
A No component is concentrated at the surface of the solution
B The component molecules are non polar and are of almost equal size
C In the formation of solution, chemical combination/molecular association between unlike molecules takes place
D The attractive forces between like and unlike molecules are almost equal
Raoult's law states that 'the equilibrium vapor pressure that is exerted by a component in a solution is proportional to the mole fraction of that component'. This generalisation is based on the assumption that the
A Sizes of the component molecules are approximately equal
B Attractive forces between like and unlike molecules are approximately equal
C Component molecules are non-polar and no chemical combination or molecular association between unlike molecules takes place in the formation of the solution
D All of the above
If the numerator of a fraction is increased by 150% and the denominator of a fraction increased by 200% fraction becomes 10/19. Find the fraction.
A 12/17
B 10/16
C 12/19
D 9/11
If 1 is added to the numerator of a fraction, the fraction becomes 1. If 1 is added to the denominator, the fraction becomes 12Find the fraction.
A 13
B 12
C 23
D 34

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